Enzymatic Production ofd-( — )-Pantoyl Lactone from Ketopantoyl Lactone
نویسندگان
چکیده
منابع مشابه
Ketopantoyl lactone and ketopantoic acid reductases. Characterization of the reactions and purification of two forms of ketopantoyl lactone reductase.
Spectral and chromatographic data as well as methods for synthesis of 14C-labeled ketopantoic acid, ketopantoyl lactone, pantoic acid, and pantoyl lactone are presented. The products of ketopantoic acid and ketopantoyl lactone reductases were characterized as pantoic acid and pantoyl lactone, respectively. Unlike pantoyl lactone, ketopantoyl lactone spontaneously hydrolyzes and has a half-life ...
متن کاملKetopantoic acid and ketopantoyl lactone reductases. Stereospecificity of transfer of hydrogen from reduced nicotinamide adenine dinucleotide phosphate.
The stereospecificity of hydrogen transfer from NADPH to the appropriate carbonyl substrate catalyzed by ketopantoic acid and ketopantoyl acid and ketopantoyl lactone reductases of yeast (Saccharomyces cerevisiae) and Escherichia coli has been determined. Yeast and E. coli ketopantoic acid reductases are B-specific enzymes which transfer hydrogen from [4B-3H]-NADPH to ketopantoic acid to form [...
متن کاملAnti - Microbial Plasma Membrane Activity of Daptomycin and Pantoyl Lactone against Streptococcus Equi
In this study, the ability of two antibiotics daptomycin and pantoyl lactone to inhibit growth of horse originated pathogen Streptococcus equi by disrupting plasma membrane of the bacterium was investigated using agar diffusion and micro tube dilution methods. The results obtained from this study indicated that daptomycin was more effective in inhibiting the growth of the pathogen in vitro than...
متن کاملAromaticine, a sesquiterpene lactone from Amblyopappus pusillus
AROMATICINE (SYSTEMATIC NAME: 4a,8-dimethyl-3-methyl-ene-3,3a,4,4a,7a,8,9,9a-octa-hydro-azuleno[6,5-b]furan-2,5-dione), C(15)H(18)O(3), is a natural lactone isolated from Amblyopappus pusillus. The mol-ecular structure and conformation agree with the results of Romo, Joseph-Nathan & Díaz [(1964 ▶). Tetra-hedron, 20, 79-85]. The fused-ring system contains a seven-membered ring in a twist-boat co...
متن کاملLactone-germination Inhibitors from Cryptocarya Moschata Seeds
( )-Cryptocaryalactone (6-[2-acetoxY-4-phenyl-3-butenyl}5,6-dihydro-2-pyranone) and ()-deacetylcryptocaryalactone (6-[2-hydroxy-4-phenyl-3-butenyIJ-5,6-dihydro-2-pyranone) isolated from Cryptocarya moschata seeds are natural germination inhibitors. Applied at 0.004 M, the second compound completely arrested germination of velvetleaf (Abulilolllheophrasli) and decreased the germination rate of s...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Agricultural and Biological Chemistry
سال: 1987
ISSN: 0002-1369
DOI: 10.1080/00021369.1987.10868529